— Ch. 1 · The Ozone Discovery —
Kigali Amendment.
~3 min read · Ch. 1 of 6
In 1974, Paul J. Crutzen, Mario Molina, and F. Sherwood Rowland revealed the harmful effects of chlorofluorocarbons on the ozone layer. These gases were widely used in industrial products like refrigerants. The scientific community quickly understood that these chemicals caused significant depletion to the protective atmospheric shield. By 1987, twenty major producers signed the Montreal Protocol to phase out these substances. The agreement officially came into effect in 1989. All one hundred ninety-seven member states of the United Nations eventually ratified this historic treaty.
HFCs Replace CFCs
Hydrofluorocarbons entered the market as a safe alternative to chlorofluorocarbons because they do not contain chlorine. This substitution meant HFCs would not damage the ozone layer further. However, scientists soon discovered these new gases acted as powerful greenhouse gases. Their lifespan in the atmosphere ranges from ten to twenty years compared to carbon dioxide. Despite their shorter life, HFCs filter infrared radiation much more powerfully than other gases. A single molecule can have a global warming potential between twelve and fourteen thousand eight hundred times that of carbon dioxide over one hundred years. Eliminating emissions of these gases could prevent half a degree Celsius of warming by the end of the century.